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Clean Hydrogen Partnership

Small explosion in a chemicals manufacturing plant

Event

Event ID
915
Quality
Description

In a plant producing calcium carbide (CaO + 3C -> CaC2 + CO), a dust collector clogged, probably due to the failure of the cleaning device (nitrogen nozzles) which allowed the dust to build a plug.
During the procedure of introducing a poker through an inspection hatch at the lower level, a small explosion occurs and a large amount of dust is ejected through the vent. The cloud containing carbon monoxide and hydrogen ignited.

The fire spread to the electrical cables supplying the equipment.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
France
Date
Component involved
off-gas system
Failure mode
rupture & ignition
Initiating cause
wrong operation
Root CAUSE analysis

The INITIATING CAUSE was the manual intervention executed to free the dust collector.
The intervention was inadequate, because executed at the wrong position (under the clogged zone) without the knowledge of the hazards involved (opening of a hatch and mixing hot reactive powders with air).
Therefore the root cause is probably related to lack of adequate procedures and/or adequate operative and safety training

Root causes
Date entry in HIAD
01/01/2018

Facility

Application
Chemical industry
Sub-application
CaC2 production
Hydrogen supply chain stage
All components affected

calcium carbide reactor and its components

Process temperature range [C]
ambient temperature (-50°C to +50°C)
Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

The dust remover of the reactor had clogged and its cleaning required a manual intervention.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
1
Post-event summary

According to source, a worker was only slightly injured by incandescent dust jets. The furnace was shut down for 25 hours and the dust collector for 15 days, during which 87 t of dust (lime) was released into the environment.
Residents were inconvenienced and traffic on the nearby highway disrupted.

Emergency action

The disaster was controlled in 15 minutes thanks to the intervention of a dozen internal
firefighters.

Lesson Learnt

Lesson Learnt

The source does not report improvement requirements. Nevertheless, the inadequate manual de-clogging intervention shows that better procedure and better safety training are needed.

In-depth data

Release type
gas mixture
Involved substances (% vol)
powder and CO+H2 mixture
Release temperature [°C]
25
Probable IGNITION SOURCE
Explosion type
Detonation

References

Sources categories
ARIA
Reference & weblink

Event description in the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/9944/
(accessed September 2020)