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Clean Hydrogen Partnership

release at a hydrocracker in a refinery plant

Event

Event ID
685
Quality
Description

The event affected the hydrocracker unit. A sudden release into a cracker compressor flare header destroyed a safety relief valve and damaged a sight glass on a liquid collection pot. As a consequence, release of hydrogen rich vapour to atmosphere occurred, necessitating a shut down of the iso-cracker.

The damage was limited to that previously described, and there were no injuries. The cracker was returned to service four days later.

Event Initiating system
Classification of the physical effects
Unignited Hydrogen Release
Nature of the consequences
leak no ignition
Macro-region
Europe
Country
United Kingdom
Date
Component involved
PRD (valve)
Failure mode
rupture, no ignition
Initiating cause
inadequate or wrong design
Root CAUSE analysis

According to the ICHEME report (see reference), the INITIATING cause was an accumulation of liquid in the flare header. The problem was compounded by undersized header and piping, and triggered by unstable operating conditions.

Considering the recommendations reported by the ICHEME report, it could be concluded that contributing or root causes were inadequacy of related design and of procedures.

Root causes
Date entry in HIAD
01/01/2021

Facility

Application
Petrochemical industry
Sub-application
Hydrocracking process
Hydrogen supply chain stage
All components affected

hydrocracker compressor and valve

Process temperature range [C]
ambient temperature (-50°C to +50°C)
Process pressure range [MPa]
medium to high pressure (10 to 50 MPa)
Location type
Semiconfined
Location
industrial area
Operational condition

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

As reported by the ICHEME report, the losses were limited to reduced production and repair costs; however, there was a potential threat to life and major equipment.

Lesson Learnt

Lesson Learnt

The following recommendations are reported (ICHEME) as lesson learnt:
1. Drain drip pots frequently to prevent liquid build-up.
2. Locate source(s) of liquid and remedy immediately, when possible, otherwise during the shutdown.
3. Ascertain any testing required for individuals exposed to high levels of noise or hazardous vapours.
4. Redesign the liquid removal system to ensure no build-up.
5. Redesign the flare header to reduce velocity and back pressure.
6. Adjust the operating and emergency procedures to reflect the dangers of rapid feed rate changes.
7. Review the maintenance requirements for compressor alarms and trips.
8. Review the refinery quality control procedures for work done in outside workshops.

In-depth data

Release type
gas
Involved substances (% vol)
H2 100%
Release temperature [°C]
25
Probable IGNITION SOURCE

References

Sources categories
ICHEME
Reference & weblink

Event description extracted from the UK database ICHEME in PDF

https://www.icheme.org/knowledge/safety-centre/resources/accident-data/
(accessed October 2020)