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Clean Hydrogen Partnership

Pipe rupture and fire at a refinery

Event

Event ID
581
Quality
Description

A series of explosions at an oil refinery reformer unit ,converting low-octane gasoline into high-octane unleaded fuel. The unit was being brought back online after a week of repairs to a compressor. The explosions were caused by a rupture to an 8 inch naphtha and hydrogen feed pipe. Fire officials cited higher than normal line pressures just before the blast. The ensuing fires were quickly contained and extinguished, but caused offsite traffic within several blocks to be stopped. As a precautionary measure, a second reformer unit was shutdown pending the investigation. A large number of injuries was due to the close proximity of a construction crew working in the area.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Component involved
pipe (generic)
Failure mode
rupture
Initiating cause
over-pressurisation
Root CAUSE analysis

The INITIATING CAUSE was the loss of confinement of a pipe carrying naphtha and hydrogen. The pipe failed at a pressure (55 bar) higher then the its operative value, but still below its design rupture value. 

This material or component degradation could be related to a manufacturing defect, or an accelerated corrosion, with an additional factor in inadequate inspection procedure and tool:  it is nevertheless impossible to identify the root cause of it.

Root causes
Date entry in HIAD
01/01/2020

Facility

Application
Petrochemical industry
Sub-application
catalytic reforming process
Hydrogen supply chain stage
All components affected

H2 supply line

Process temperature range [C]
High temperature (100°C to 500°C)
Process pressure range [MPa]
medium pressure (2 to 10 MPa)
Location type
Open
Location
industrial area
Operational condition
Pre-event occurrences

The reformer was being brought back on line after being shutdown for several weeks for repairs.

Emergency & Consequences

Number of fatalities
3
Number of injured persons
45
Post-event summary

Two of the affected memebrs of the crew were declared dead at the scene. and a further one later in hospital. Amonge the injured workers, ten people were initially in critical condition, with many suffering severe burns. Several victims were contractors working on the unit during its startup.

Emergency action

The ensuing fires were quickly contained and extinguished, but caused offsite traffic within several blocks to be stopped.

In-depth data

Release type
gas
Involved substances (% vol)
H2 100%
Probable IGNITION SOURCE
Explosion type

References

Sources categories
News
Reference & weblink

UPI news of Dec 5, 1985 https://www.upi.com/Archives/1985/12/05/A-series-of-explosions-thundered-through-an-Arco-Oil/3115502606800/#:~:text=By%20SUSAN%20SEAGER,John%20Maleta%20said. (accessed Feb 2026)

UPI news of Dec 7, 1985 https://www.upi.com/Archives/1985/12/07/Investigators-Saturday-tentatively-blamed-a-weakpipe-for-the-cause/3606502779600/#:~:text=%2D%20UPI%20Archives-,Investigators%20Saturday%20tentatively%20blamed%20a%20weakpipe%20for%20the%20cause...,%27(accessed Feb 2026)

Los Angeles Times of 6 December 1985

APN news of 06 December 1985https://www.apnews.com/1caf3098e31244fbb9f2fa32ea1b314c (Accessed May 2020)