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Clean Hydrogen Partnership

Hydrogen explosion in a metal processing pla

Event

Event ID
106
Quality
Description

The event took place at the metal sheet pre-heating oven of a galvanization unit. This was using a mixture of hydrogen and nitrogen to form a reducing atmosphere and avoid oxydation of the metallic sheets.
The zinc crucible’s draining operations was completed and the hydrogen purge operation which had been started 6 hours earlier, was underway when an explosion happened.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
France
Date
Component involved
reactor / oven / furnace / test chamber
Failure mode
internal explosion
Initiating cause
wrong operation
Root CAUSE analysis

The INITIATING CAUSE was due to the fact that the valve on the backup hydrogen tank and the by-pass on the furnace’s supply line were not closed. A hot spot in the oven probably ignited the explosive atmosphere.

No information is available on the ROOT CAUSE, but probably related to shortcomings of the procedures and/or an operator error.

Root causes
Date entry in HIAD
28/02/2009

Facility

Application
Steel and metals industry
Sub-application
generic metal processing
Hydrogen supply chain stage
All components affected

Pre-heating oven for metal sheets

Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

The oven had been shut down the previous evening for annual maintenance work.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

The four employees present were not injured. No impact outside the site was reported.

Emergency action

probably none,due to the velocity of the event.

Lesson Learnt

Corrective Measures

Following the accident, the operator modified the procedures concerning these operations by:
(1) Blinding of the by-pass and leak test,
(2) modifying the valve of the back-up H2 circuit to allow lock-out capability.

In-depth data

Release type
gas mixture
Involved substances (% vol)
H2
N2
Probable IGNITION SOURCE
Explosion type

References

Sources categories
ARIA
Reference & weblink

Event No, 30365 of the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/30365/
(accessed December 2020)