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Clean Hydrogen Partnership

Event

Event ID
161
Quality
Description

The event occurred at the in the distillate hydrotreater unit of a refinery. This unit removed sulphur from a hydrocarbon feedstock by hydogenating it with hydrogen. A 12-inch overhead pipe ruptured with a loud noise and released flammable gaseous hydrocarbonsat a temperature high enough to cause spontaneous ignition.
The pipe normally operated at a pressure of approximately 600 pounds per square inch (approximately 40 bar). No personnel were present in the unit when the pipe rupture occurred.
The local fire brigade extinguished the ensuing fire two hours later. No employees or emergency responders were injured. Air monitoring at the perimeter of the refinery did not detect elevated concentrations of any hazardous chemicals.

The fire damage was confined to other equipment in an area of to an approximately 10 square meter. Two fan-type heat exchangers were destroyed by the fire along with an approximately 50-foot section of piping; electrical conduit was also damaged by radiant heat. No blast damage was observed.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
North America
Country
United States
Date
Component involved
pipe (generic)
Failure mode
rupture & ignition
Initiating cause
material degradation (internal corrosion / erosion)
Root CAUSE analysis

The cause of the pipe rupture could not be determined. Nevertheless, the investigation noted there have been a number of past instances of corrosion-related failures in refinery hydrotreater units.

Root causes
Date entry in HIAD
28/02/2009

Facility

Application
Petrochemical industry
Sub-application
Hydrodesulphurisation process
Hydrogen supply chain stage
All components affected

gas recycle line

Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

the investigation reported that there have been a number of past instances of corrosion-related failures in refinery hydrotreater units.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

The fire damage was confined to other equipment in an area of to an approximately 10 square meter. Two fan-type heat exchangers were destroyed by the fire along with an approximately 50-foot section of piping; electrical conduit was also damaged by radiant heat. No blast damage was observed.

Air monitoring at the perimeter of the refinery did not detect elevated concentrations of any hazardous chemicals.

Emergency action

The local fire brigade extinguished the ensuing fire two hours later. No employees or emergency responders were injured. Air monitoring at the perimeter of the refinery did not detect elevated concentrations of any hazardous chemicals.

Lesson Learnt

Lesson Learnt

In general, it is important to carefully guarantee the integrity of piping that contains hazardous substances through rigorous inspection and testing, and to adapt them with increasing ageing of the components.

In-depth data

Release type
Liquid
Involved substances (% vol)
H2 100%
Probable IGNITION SOURCE

References

Sources categories
News
Reference & weblink

HeraldGuide news of 21 May 2006:
https://www.heraldguide.com/news/investigation-of-valero-explosion-comp…
(accesed January 2024)