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Clean Hydrogen Partnership

Fire during LH2 transfer

Event

Event ID
1124
Quality
Description

A LH2 trailer was delivering at a customer location. The LH2 transfer had just been terminated and the driver was ready to depressurise the trailer to remove the hose.
When he started to open the vent valve, the relief system diverter valve came apart. The escaping hydrogen caught fire. The vacuum caps located on the top, rear of the trailer (above the cold end of the trailer) and the top front of the trailer were dislodged and fire proceeded to come out of the openings.

The local fire-fighters arrived on scene in less than 10 minutes, followed by the emergency medical service. The company sent a safety specialist to the scene.
The fire-fighters were instructed to use unmanned hoses and to keep water on the customer stationary storage vessel, the LH2 trailer and the tractor, and to wait for fire in the trailer to burn itself out. The following morning, approximately 15 hours after the start of the emergency, flames were no longer evident. One hour later, the company safety specialist on the scene and the fire department declared the scene secure.

The investigation concluded that:
(1) Ambient air entered the system by diffusion and convection, in quantity enough to start combustion.
(2) This ambient air condensed and froze as it approached the trailer's inner vessel.
(3) The solid frozen air was trapped in the piping connected to the vessel nozzle.
(4) When the driver turned the 2" vent valve open to a high discharge rate to depressurize the trailer, the solid frozen air was disturbed and sufficient friction caused an ignition of the hydrogen and air in the piping connected to the nozzle.
(5) A detonation occurred in the horizontal piping causing a facture at the nozzle

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
North America
Country
United States
Date
Component involved
PRD (valve)
Failure mode
rupture & ignition
Initiating cause
unknown
Root CAUSE analysis

INITIATING CAUSE: loss of confinement causing air to access the liquid hydrogen vessel.
Several details of the incident remain unexplained. For example, where the location and the modalities for air to access the vessel, or why the vacuum caps were involved in the fire.
ROOT CAUSE: unknown, although a material failure causing such consequences should have been considered in the safety design (risk assessment). This hints at some shortcoming in the technical mitigating measures of the system.

Root causes
Date entry in HIAD
09/09/2024

Facility

Application
Hydrogen transport and distribution
Sub-application
LH2 tanker
Hydrogen supply chain stage
All components affected

hose, connection, vent valve

Process temperature range [C]
cryogenic temperature (below -50°C)
Process pressure range [MPa]
low to medium pressure (below 2 MPa)
Location type
Open
Location
highway or similar
Operational condition
Pre-event occurrences

The drive had just terminated the LH2 transfer from the trailer to the stationary tank.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
2
Currency
US$
Property loss (onsite)
912.900
Post-event summary

Both drivers were evaluated on site and taken by ambulance to local hospitals for further evaluation.
Approximately 1600 kg of LH2 were lost.

Emergency action

The local fire-fighters arrived on scene in less than 10 minutes, followed by the emergency medical service.
The company was in phone contact with the teams on the site, until their safety specialist arrived at the scene. The fire-fighters were instructed to use unmanned hoses and to keep water on the customer stationary storage vessel, the LH2 trailer and the tractor, and to wait for fire in the trailer to burn itself out. The also succeed to reach the location of an to activate the emergency shut-off button of the site

The following morning, approximately 15 hours after the start of the emergency, flames were no longer evident. One hour later, the company safety specialist on the scene and the fire department declared the scene secure.

In-depth data

Release type
gas
Involved substances (% vol)
H2 100%
Released amount (kg)
1609.008327025
Probable IGNITION SOURCE

References

Sources categories
PHMSA
Reference & weblink

Incident I-2012030031 of the US Pipeline and Hazardous Materials Safety Administration PHMSA:
https://portal.phmsa.dot.gov/analytics/saw.dll?Portalpages&PortalPath=%…
(accessed September 2024)