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Clean Hydrogen Partnership

Fire at the desulphurisation unit of a refinery

Event

Event ID
613
Quality
Description

The explosion occurred during preparatory work to start a compressor that supplies hydrogen gas to a heavy oil direct desulfurization unit. The inspection cover of the crank case came off, injuring an operator.
Normally, nitrogen was supplied to purge the case , displacing the hydrogen leaking from the shaft seal of the compressor cylinder. The accident investigation revealed that the nitrogen flow meter was broken, causing almost no gas to flow.
It is assumed that the hydrogen leaking from the shaft seal of the cylinder entered the crankcase, ignited and burned due to static electricity. The expansion force of the explosion caused the inspection cover of the crankcase to fly off.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Asia
Country
Japan
Date
Component involved
compressor / booster / pump (piston)
Failure mode
internal explosion
Initiating cause
inadequate or no purge
Root CAUSE analysis

The INITIATING CAUSE was the failing of the nitrogen system supposed to purge the compressor crankcase free of hydrogen.
The failure to purge was due to a broken flow metre which was indicating nitrogen flow while almost no nitrogen was flowing
The ROOT CAUSE was a lack of proper inspection and maintenance.

Root causes
Date entry in HIAD
01/05/2025

Facility

Application
Petrochemical industry
Sub-application
Hydrodesulphurisation process
Hydrogen supply chain stage
All components affected

flow meter, shaft seal,
compressor cylinder,
crankcase,
H2 compressor

Process temperature range [C]
ambient temperature (-50°C to +50°C)
Process pressure range [MPa]
unknown
Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

Preparatory operation was ongoing for the start of a hydrogen compressor

Emergency & Consequences

Number of fatalities
0
Number of injured persons
1
Post-event summary

minor injury

Lesson Learnt

Lesson Learnt

This is an incident cause by the wrong indication of an instrument, which was a critical component of preventing measures of the system. Special attention should be given to the proper functioning of components critical to safety. Effective check/inspection shall be in place to detect early enough malfunctioning. Moreover, redundancy could be provided, for example by installing two components with the same function.

In-depth data

Release type
gas
Involved substances (% vol)
H2 100%
Release temperature [°C]
25
Probable IGNITION SOURCE
Explosion type

References

Sources categories
KHK
Reference & weblink

High Pressure Gas Accident Cases Database of the KHK (High Pressure Gas Safety Association):
https://www.khk.or.jp/public_information/incident_investigation/hpg_inc…
(accessed May 2025)

The first entry in HIAD was coming from RISCAD, which is now closed.