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Clean Hydrogen Partnership

Explosion on a cold box

Event

Event ID
663
Quality
Description

An explosion occurred in a nitrogen wash cold box (outside the equipment) after a several day cold shutdown followed by a derime with nitrogen. It is assumed that ice may have split tubes permitting carbon monoxide and hydrogen to leak into the perlite installation. It is likewise assumed that the insulation had channelled and had many voids.
However, the insulation was continuously purged with nitrogen and the mechanism of the explosion is still unknown.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Component involved
pipe (weld)
Failure mode
rupture & ignition
Initiating cause
material degradation (generic)
Root CAUSE analysis

The INITIATING CAUSE were cracks in aluminium welds which leaked hydrogen cumulating in the cold box.

A CONTRIBUTING FACTOR was the cold weather which could have caused the formation of ice. Since the cold box thermal insulation, consisting of perlite, was purged with nitrogen, it is unclear why hydrogen and CO could form an explosive atmosphere.

The ROOT CAUSE is not provided. It could nevertheless plausibly attributed to design and/or manufacturing (welding) error.

Root causes
Date entry in HIAD
01/01/2020

Facility

Application
Chemical industry
Sub-application
cryogenic separation of H2 feed gas
Hydrogen supply chain stage
All components affected

cold box

Process temperature range [C]
cryogenic temperature (below -50°C)
Location type
Unknown
Location
unknown
Operational condition
Description of the facility/unit/process/substances

DECRITION OF THE PROCESS
A "derime" is a maintenance procedure used to remove frozen impurities from a cryogenic system, such as a nitrogen or air separation unit. This is done by warming up the equipment and flowing a warm, dry gas through it to melt and purge any accumulated moisture, carbon dioxide, or other contaminants that would otherwise freeze and block the system. The terms "derime," "defrost," "de-ice," and "thaw" are often used interchangeably for this process.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Currency
US$
Property loss (onsite)
1.900.000

In-depth data

Release type
gas mixture
Involved substances (% vol)
H2
CO
Probable IGNITION SOURCE
Explosion type

References

Sources categories
ICHEME
Reference & weblink

Event description extracted from the UK database ICHEME in PDF.
The
https://www.icheme.org/knowledge/safety-centre/resources/accident-data/
(accessed October 2020)

Table III of Appendix A of Zalosh and Short
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978
https://www.osti.gov/biblio/6566131
(accessed September 2020)

LOSS PREVENTION, VOL. 3.