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Clean Hydrogen Partnership

Deflagration in a ammonia synthesis unit

Event

Event ID
90
Quality
Description

A deflagration occurred during shutdown of a reactor used for ammonia synthesis. It was followed by a jet fire.
The hydrogen leak was probably due first to the lower seals, followed by another leak on the upper seal of the autoclave, under 15 to 20 bars.

The Internal Operation Plan is launched and cancelled 1h50 later. No one is injured.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
France
Date
Component involved
reactor / oven / furnace / test chamber
Failure mode
leak & ignition
Initiating cause
unknown
Root CAUSE analysis

INITIATING cause was the leak of a joint of an autoclave. Nothing known on the root cause(s).

Root causes
Unknown
Date entry in HIAD
28/02/2009

Facility

Application
Chemical industry
Sub-application
Fertilisers production
Hydrogen supply chain stage
All components affected

autoclave, seals of joints

Process temperature range [C]
High temperature (100°C to 500°C)
Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

The leak occurred during maintenance operation

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Emergency action

The explosion was followed by a jet fire. The Internal Operation Plan was launched and terminated 1h50 later.

In-depth data

Release type
Liquid
Involved substances (% vol)
H2 100%
Probable IGNITION SOURCE
Explosion type
Flame type

References

Sources categories
ARIA
Reference & weblink

Event no. 31715 of the French database ARIA (accessed December 2020)