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Clean Hydrogen Partnership

Explosion at a water treatment facility

Event

Event ID
1080
Quality
Description

This incident occurred when subcontractor two workers were widening air vents on the roof of a building hosting a tank containing hydrogen chloride solution. This intervention was necessary to to improve hydrogen venting from the tank storage area. The hydrogen gas was a by-product of the chlorine-making process.
The two workers were operating an angle grinder, producing sparks which ignited the flammable atmosphere which evidently containing hydrogen. An explosion followed, with one casualty and one injured worker.
The HSE, in charge of the investigation, concluded: "The company failed to take adequate steps to prevent the risk of an explosion occurring during the construction work that was taking place at the plant near to a source of hydrogen gas."

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
United Kingdom
Date
Component involved
chemical storage tank (HCl)
Failure mode
rupture & ignition
Initiating cause
inadequate or no purge
Root CAUSE analysis

The incident inquiry by the Health and Safety Executive found that the water service company was to blame for management shortcoming in risk assessment, safety measures implementation, operative procedures, and management of external workers. The workers were unaware of the existence of hydrogen gas or the hazards involved, and that they did not see any health and safety or danger signs on the building.

Root causes
Date entry in HIAD
01/07/2024

Facility

Application
Other
Sub-application
waste management
Hydrogen supply chain stage
All components affected

vent, tank

Process temperature range [C]
ambient temperature (-50°C to +50°C)
Location type
Confined
Location
industrial area
Operational condition
Pre-event occurrences

The involved tanks were originally installed as an open-air facility, which was self-venting. However, the company decided to create a building around it, to avoid exposure to the elements.

Emergency & Consequences

Number of fatalities
1
Number of injured persons
1

Lesson Learnt

Lesson Learnt

These were the findings of the forensic investigation:
(1) The explosion occurred because of a build-up of hydrogen in the ducting beneath the roof, likely ignited by the grinder.
(2) The plant should have been shut down.
(3) No permit had been given for the work being carried out.
(4) A specific risk assessment should have been carried out, but had not been done.
(5) The area should have been verified safe, for example by means of gas detectors.
(6) Safety and hazard warning signs would have helped, but none were present on the roof of the building, and that there were very poor communication channels.
(7) That tanks involved should not have been enclosed (they were originally installed as an open-air facility, which was self-venting. However, the company had decided to create a building around it. to avoid exposure to the elements).
(8) Gas detectors should have been provided.
(9) The workers should have been supervised by the plant operator.

In-depth data

Release type
gas mixture
Involved substances (% vol)
H2,
Cl2
Release temperature [°C]
25
Probable IGNITION SOURCE
Explosion type

References

Sources categories
News
Reference & weblink

Irish Times news of 6 Dec 2006
(accessed aug 2023)

BBC news of 7 Dec 2006
https://www.irishexaminer.com/news/arid-30288410.html
(accessed aug 2023)

PSI Database ENSAD
https://www.psi.ch/en/ta/ensad
(not online since 2024)

Irish Examiner news of 6 Dec 2006
https://www.irishexaminer.com/news/arid-30288410.html
(accessed aug 203)