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Clean Hydrogen Partnership

Fire on a hydrogen compressor of refinery

Event

Event ID
1070
Quality
Description

A fire broke out at a hydrogen compressor of the reforming unit of the refinery.
Following the safety procedures, the emergency stop of the unit was activated and the unit was decompressed using a safety flare. The emergency plan was kept for an hour. A security perimeter is in place. The isolation of the compressor was started automatically. The isolation of the discharge circuit was successful, but the suction circuit could only be partially closed due to a block of a valve. The operators then closed manually the suction valve, by removing the excess of grease that had been applied to it. Nitrogen was injected into the suction circuit, to replace the still burning hydrogen. The gas detection system set up did not reveal any explosive atmosphere near the equipment.

The leak of the oil/hydrogen mixture is estimated at 500 kg.

Shortly before the event, during planned work, an unplanned tripping of the 400 V low voltage electrical panel had caused a loss of electrical power to the reforming unit. The triggering was due to the presence of an electrical bypass which had been left in the “test” position.
The event sequence occurred as follows:
1. The lack of power supply caused the stop of the oil pump of the compressor. Another turbine-driven pump with the same role did not take over because it had not been foreseen its start-up in the event of a loss of electrical power.
2. The very low oil level caused the compressor to stop.
3. Hydrogen migrated through the sealing into the oil circuit, causing a pressure build-up. The final consequence was then the loss of containment of the oil and hydrogen mixture at the level of the motor of the valves regulating the inlet steam to the turbine. The release hydrogen quickly ignited.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
Europe
Country
France
Date
Component involved
compressor / booster / pump
Failure mode
rupture & ignition
Initiating cause
malfunctioning (electrical/electronic component)
Root CAUSE analysis

The INITIATING cause was the lack of power, which triggered a series of events in the hydrogen compressor which allowed hydrogen leaking into oil and causing loss of containment.
The escalation could have been avoided if the redundancy in oil pumping could have been used also in case of loss of power.
When mitigating the consequence, the procedures in place where well followed, but a material failure (valve not closing) was possible the consequence of inspection or maintenance or installation shortcomings.

Root causes
Date entry in HIAD
01/07/2024

Facility

Application
Petrochemical industry
Sub-application
Steam methane reforming
Hydrogen supply chain stage
All components affected

power supply,
hydrogen compressor,
oil pump,
oil circuit,
valves

Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

Shortly before the event, during planned work, an unplanned tripping of the 400 V low voltage electrical panel had caused a loss of electrical power to the reforming unit.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

The leak of the oil/hydrogen mixture is estimated at 500 kg.

Emergency action

1. the emergency stop of the unit was activated and the unit was decompressed using a safety flare.
2. The emergency plan was kept for an hour. A security perimeter is in place.
3. The isolation of the compressor started automatically. However, manual intervention was necessary to close completely one of the two insolation valves.
4. Nitrogen was injected into the suction circuit, to replace the still burning hydrogen.
5. The gas detection system was set up and did not reveal any explosive atmosphere near the equipment.

Lesson Learnt

Lesson Learnt

The emergency procedures in place were correctly followed and demonstrated their effectiveness in mitigating the effects of the fire.

The source does not report any corrective action. Based on the sequence of sub-events following the loss of power, a possible recommendation could be to perform a new risk assessment including the occurred accidental scenario, and develop better preventing/mitigating measures. One of this could to guarantee continuity of oil pumping power.

In-depth data

Release type
Gas-liquid mixture
Involved substances (% vol)
H2 ,
oil
Probable IGNITION SOURCE

References

Sources categories
ARIA
Reference & weblink

Event 59706 of the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/59706/
(accessed July 2023)