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Clean Hydrogen Partnership

Fire in a chemical factory

Event

Event ID
1067
Quality
Description

A fire broke out following a hydrogen leak on the Cyclododecane unit in a chemical plant.
A plume of smoke became visible outside the site. The fire was brought under control by putting the unit in safe mode, implementing the internal resources available on site (monitor lance, sprinkler ring and extinguishers), and finally by the intervention of the internal firefighters. The staff was evacuated and the internal crisis unit triggered. The fire was extinguished in 30 minutes.

The post-incident analysis revealed a hole in the connection of the vent manifold, upstream of the evacuation pipe. The failure was caused by external corrosion under the thermal insulation layer. It caused a hydrogen leak and a flow of Cyclododecane. The released hydrogen auto-ignited and the fire spread to the Cyclododecane.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
Europe
Country
France
Date
Component involved
pipe (generic)
Failure mode
rupture & ignition
Initiating cause
material degradation (external corrosion)
Root CAUSE analysis

The INITIATING cause was the failure of a connection due to external corrosion. The presence of a thermal insulation layers around the piping did not allow for a visual inspection of the components.
This is a well-known cause for corrosion to proceeded to full component failure, and suggest a ROOT CAUSE related to a inadequate inspection/maintenance procedures and tools.

Root causes
Date entry in HIAD
01/07/2024

Facility

Application
Chemical industry
Sub-application
cyclododecane production
Hydrogen supply chain stage
All components affected

furnace, exhust pipe

Location type
Unknown
Location
industrial area
Operational condition

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

The operator noted only material damage. The water used to extinguish the fire was safely stored.

Emergency action

The fire was brought under control by putting the unit i in safe mode, implementing the internal resources available on site (monitor lance, sprinkler ring and extinguishers), and finally by the intervention of the internal firefighters. The staff was evacuated and the internal crisis unit triggered. The fire was extinguished in 30 minutes.

Lesson Learnt

Corrective Measures

Following the event, the operator implemented the following actions:
• To repair of all vent collectors and the evacuation pipe;
• To add an alarm on the relative concentrations between raw materials, to detect over-consumption of hydrogen;
• To add an audible and visual alarm locally in the workshop in case of fire;
• To inform of the event all production teams.

In-depth data

Release type
Gas-liquid mixture
Involved substances (% vol)
H2,
cyclododecane
Probable IGNITION SOURCE

References

Sources categories
ARIA
Reference & weblink

Event 58702 of the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/58702/
(accessed July 2023)