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Clean Hydrogen Partnership

hydrogen and hydrocarbon release in a refinery

Event

Event ID
999
Quality
Description

The incident occurred at a reactor vessel of a naphtha hydrotreater unit. The vessel operated at around 25 bar and 140 C. A 1.5-meter crack opened up in the reactor vessel close to welded vessel support, causing the release of hot naphtha and hydrogen, which created a vapour cloud and ignited, leading to an explosion and fire. The explosion caused releases from other parts of the plant, including a nearby diesel hydrotreater, which contributed to the fire.
Eight on-site employees were injured, but there were no fatalities.
Residents of a nearby town were evacuated as a precaution.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
Germany
Date
Component involved
reactor / oven / furnace / test chamber
Failure mode
rupture & ignition
Initiating cause
unknown
Root CAUSE analysis

The INITIATING/direct cause was the opening of crack. Details are missing for an accurate conclusion on the cause.

Root causes
Unknown
Date entry in HIAD
01/01/2024

Facility

Application
Petrochemical industry
Sub-application
Hydrodesulphurisation process
Hydrogen supply chain stage
All components affected

reactor vessel

Process temperature range [C]
High temperature (100°C to 500°C)
Location type
Open
Location
industrial area
Operational condition
Description of the facility/unit/process/substances

DESCRIPTION OF THE PROCESS
The refinery started operation in 1967. The plant is located near the river Donau. It receives crude oil from a pipeline and processes it into gasoline, diesel fuel, heating oil, kerosene, bitumen and sulphur.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
12
Currency
US$
Property loss (onsite)
824.000.000
Property loss (offsite)
4.900.000
Post-event summary

Some refinery process units were extensively damaged as a result of the explosion and fire, as well as multiple office and maintenance buildings within the refinery site. Windows in a village at least 3km away were broken.
The quantities released: 70 t of hydrocarbon and 0.3 t of hydrogen.
A different source assesses the total damage to 770 M$ corresponding to 879 M$ of 2021. Unclear how this was calculated.

Emergency action

Several hundred firefighters were reportedly deployed to
control the fire.

In-depth data

Release type
Gas-liquid mixture
Involved substances (% vol)
H2,
naphta
Release temperature [°C]
140
Probable IGNITION SOURCE
Explosion type

References

Sources categories
Collections
Reference & weblink

MARSH report, 100 largest losses in the hydrocarbon industry, 27th edition 2022
https://www.marsh.com/cz/en/industries/energy-and-power/insights/100-la…
(accessed January 2024)

From European database eMARS
https://emars.jrc.ec.europa.eu/en/emars/accident/view/848b91b1-b27d-11e…
(accessed December 2020)

NordBayern news of 28 November 2018:
https://www.nordbayern.de/region/reaktor-riss-schuld-an-bayernoil-explo…
(accessed January 2024)

Donaukurier video:
https://www.youtube.com/watch?v=XXbByxpY8wc
(accessed Janury 2024)