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Clean Hydrogen Partnership

Hydrocarbons fire in a refiner

Event

Event ID
987
Quality
Description

During a work tour on a refinery, an employee noticed a fire at the level of a flange at the inlet of the grille of an exchanger, located at the outlet of a reactor of the catalytic reforming unit.

The plant operator detected a lack of uniformity of torque on the bolts. Two years before, during a shutdown period, some parts of the exchanger had been removed for inspection. The flange on the heat exchanger side was not easily accessible. During reassembly, the presence of a pipe tee near the flange made it difficult to tighten with a bolting machine. The faulty tightening (1.5 mm opening) could have led to the leakage of high-octane gasoline, mixed with hydrocarbon gases and hydrogen. Without a hot spot nearby, this 500°C fluid could have spontaneously ignited on contact with air.
The plant operator tightened the flange and modified procedures to specify the use of a suitable wrench for the configuration. The operator also planned to carry out independent checks on the quality of the connections made.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
Europe
Country
France
Date
Component involved
flange (generic)
Failure mode
rupture & ignition
Initiating cause
loss of tightness (wrong operation)
Root CAUSE analysis

The INITIATING cause was the ignition of leaked mixture of hydrocarbons, including hydrogen. The INTERMEDIATE or ROOT CAUSE could have been the lack of tightness of a flange caused by a not-properly tightening of the bolts. Finally, A CONTRIBUTING or ROOT CAUSE was the difficulty of re-assembling of the system due to design.

Root causes
Date entry in HIAD
01/01/2024

Facility

Application
Petrochemical industry
Sub-application
Catalytic reforming processes
Hydrogen supply chain stage
All components affected

reformer, heat exchanger, flanges, bolts

Process temperature range [C]
Very high temperature (500°C to 1000°C)
Location type
Unknown
Location
industrial area
Operational condition

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0

Lesson Learnt

Lesson Learnt

The quality of the event description does not allow for a detailed lesson learnt. nevertheless, better operative/maintenance procedures and a (better) reporting system shall be part of it.

Corrective Measures

The plant operator modified procedures to specify the use of a suitable wrench for the configuration.
The operator also planned to carry out independent checks on the quality of the connections made.

In-depth data

Release type
gas mixture
Involved substances (% vol)
gasoline,
hydrocarbons,
H2
Release temperature [°C]
500
Probable IGNITION SOURCE

References

Sources categories
ARIA
Reference & weblink

Event description no 55225 in the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/55225_en/?lang=…
(accessed October 2021)