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Clean Hydrogen Partnership

Fire in a fertiliser plant

Event

Event ID
984
Quality
Description

the fire was detected by an employee during the normal inspection tour. It was caused by the ignition of a leak of process gas (hydrogen, methane and water vapour) from the reforming furnaces.
The plant operator stopped the ammonia unit by manually triggering the safety emergency procedure. The natural gas supply was cut off, and this immediately extinguished the flame.

The nitric acid unit was kept running at minimum rate. The hot ammonium nitrate solution and ammonium nitrate units are shut down due to lack of ammonia.
The nitric acid production unit was restarted in the morning, the ammonium nitrate unit the following day.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
Europe
Country
France
Date
Component involved
reactor / oven / furnace / test chamber
Failure mode
rupture & ignition
Initiating cause
unknown
Root CAUSE analysis

The ARIA report does not provide any cause analysis. This incident is very similar to the one described in HIAD event 983, which occurred in the same plant in 2019.

Root causes
Unknown
Date entry in HIAD
01/01/2024

Facility

Application
Chemical industry
Sub-application
Fertilisers production
Hydrogen supply chain stage
All components affected

reformer

Process temperature range [C]
High temperature (100°C to 500°C)
Location type
Open
Location
industrial area
Operational condition
Pre-event occurrences

This incident is very similar to the one described in HIAD event 983, which occurred in the same plant in 2019.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

The only consequence was the temporary reduction of the production of ammonium nitrate (H₄NO₃) and fertilisers due to lack of ammonia.

Lesson Learnt

Lesson Learnt

This incident is very similar to the one described in HIAD event 983, which occurred in the same plan in 2019. At that time, the leak had been found on a gasket, and all the gasket of the same furnace were replaced.

The description of the event in ARIA (see references) does not contain enough details to understand incident causes and deduce a lesson learnt. One general observation can be issued: despite the enormous progress achieved in safety records of hydrogen in industrial processes, attention to preventive measures is still required.

In-depth data

Release type
gas mixture (syngas)
Involved substances (% vol)
syngas
Probable IGNITION SOURCE

References

Sources categories
ARIA
Reference & weblink

Event description no 55060 in the French database ARIA (accessed October 2021)