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Clean Hydrogen Partnership

Hydrogen leak on a fuel cells bus

Event

Event ID
972
Quality
Description

The event occurred in a bus garage, while emptying and purging hydrogen tanks on board of a fuel cells and hydrogen bus. This process was necessary before staring bus preventive maintenance and was executed via an electronic control system. However, the solenoid valve one of the tanks was mechanically stuck. In these cases, the valve manufacturer had foreseen an alternative manual process using an override tool. The process was executed according to manufacturer’s instruction, but the valve still did not open to evacuate hydrogen.
The fuel cell engineer tried to rectify the problem and started removing the override tool, but forgot to unwind the stem. The sealing O-ring of the tool was damaged and caused a hydrogen release in the vicinity of the manual override tool.

The building was evacuated, the extraction fans set manually and the main shutters open to assist with ventilation and dilution of the hydrogen leak.
During the incident the emergency services were alerted. The fire brigade could monitor hydrogen concentration. The highest hydrogen level recorded was 46% of the lower flammable limit on one sensor located directly above the leak.
therefore levels were judged acceptable from an explosive risk perspective.

Approximately 5 hours later the fire brigade left the site and the depot retuned to normal business, but still subject to the control actions until depletion of the remaining hydrogen.

Event Initiating system
Classification of the physical effects
Unignited Hydrogen Release
Nature of the consequences
leak no ignition
Macro-region
Europe
Country
United Kingdom
Date
Component involved
valve (gasket)
Failure mode
rupture, no ignition
Initiating cause
malfunctioning (electrical/electronic component)
Root CAUSE analysis

The INITIATING CAUSE, as established by the investigation of the valve manufacturing, was a broken wire of the solenoid coil.

Contributing cause was the failing of the manual override tool process to release the hydrogen from the tank. What it followed was an error by the engineer in an attempt to dismantle the manual tool. This caused the damage of an O-ring.

Root causes
Date entry in HIAD
01/01/2018

Facility

Application
Road vehicles
Sub-application
FCEV-bus
Hydrogen supply chain stage
All components affected

on-board compressed hydrogen storage

Process temperature range [C]
ambient temperature (-50°C to +50°C)
Process pressure range [MPa]
medium to high pressure (10 to 50 MPa)
Location type
Confined
Location
populated area
Operational condition
Pre-event occurrences

The bus was in the garage (depot) for defueling.
The manual purging process had been previously undertaken unsuccessfully a few times by the fuel cell engineers. This was a rare, but not exceptional process.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

There has not been any consequence.

Investigation comments

The bus company requested by the valve manufacturer to investigate the solenoid valve and to issue a report.

Emergency action

The building was evacuated, the extraction fans set manually and the main shutters open to assist with ventilation and dilution of the hydrogen leak.

During the incident the emergency services were alerted. The local fire brigade put a 50 metre cordon round the fuel cell building until the hydrogen levels subsided. Hydrogen detectors were installed in the depot. The fire brigade could therefore monitor the levels in the workshop atmosphere and judged it as acceptable from an explosive risk perspective. The highest hydrogen level recorded was 46% of the lower flammable limit on one sensor located directly above the leak.

Approximately 5 hours later the fire brigade left the site and the depot retuned to normal business, but still subject to the control actions until depletion of the remaining hydrogen. Before leaving the scene, the fire brigade agreed the following with the buses company:
1. The fuel cell building would remain cordoned off.
2. The hydrogen detection panel would check every hour and the hydrogen levels recorded until they reached zero.
3. The fuelling compound would not be turned on until as late as possible.
The above three actions were undertaken and it was noted that in the early morning of the day after no hydrogen was detected in the hydrogen fuel cell workshop.

Emergency evaluation

A further consideration was the possibility of air getting into cylinder once the pressure stabilised potentially causing a flammable environment, although there would be no ignition source. This was relayed to the local fire brigade, and after discussion it was decided that the risk was low. Nevertheless it was agreed that the cylinder would be purged with nitrogen.

Lesson Learnt

Lesson Learnt

According to the valve manufacturer,
(1) the solenoid valves of the type mounted on the buses were not fabricated anymore, but were still supported and did not represent any additional hazard than their new version.
(2) The manual tool was safe provided the instructions were thoroughly followed.
To ensure that this will happen in the future, a new detailed procedure was issued in case of failure of the solenoid valve. One new procedure step is the execution of the manual operation outside the depot, to ensure maximal hydrogen dispersion.

This incident is basically a near miss with non negligible hydrogen release) highlights the difficult to build a trustful supply chain for all components and sub-components i an period in which the components and systems have not yet achieved the mass production rates making easy quantification of failure statistics and identification of all possible failure modes.

In-depth data

Release type
gas
Involved substances (% vol)
H2 100%
Release temperature [°C]
25
Probable IGNITION SOURCE

References

Sources categories
Investigation report
Reference & weblink

Provided to JRC by the operator of the facility (confidential)