Event
- Event ID
- 915
- Quality
- Description
In a plant producing calcium carbide (CaO + 3C -> CaC2 + CO), a dust collector clogged, probably due to the failure of the cleaning device (nitrogen nozzles) which allowed the dust to build a plug.
During the procedure of introducing a poker through an inspection hatch at the lower level, a small explosion occurs and a large amount of dust is ejected through the vent. The cloud containing carbon monoxide and hydrogen ignited.The fire spread to the electrical cables supplying the equipment.
- Event Initiating system
- Classification of the physical effects
- Hydrogen Release and Ignition
- Nature of the consequences
- Macro-region
- Europe
- Country
- France
- Date
- Component involved
- off-gas system
- Failure mode
- rupture & ignition
- Initiating cause
- wrong operation
- Root CAUSE analysis
The INITIATING CAUSE was the manual intervention executed to free the dust collector.
The intervention was inadequate, because executed at the wrong position (under the clogged zone) without the knowledge of the hazards involved (opening of a hatch and mixing hot reactive powders with air).
Therefore the root cause is probably related to lack of adequate procedures and/or adequate operative and safety training- Root causes
- Date entry in HIAD
- 01/01/2018
Facility
- Application
- Chemical industry
- Sub-application
- CaC2 production
- Hydrogen supply chain stage
- All components affected
calcium carbide reactor and its components
- Process temperature range [C]
- ambient temperature (-50°C to +50°C)
- Location type
- Unknown
- Location
- industrial area
- Operational condition
- Pre-event occurrences
The dust remover of the reactor had clogged and its cleaning required a manual intervention.
Emergency & Consequences
- Number of fatalities
- 0
- Number of injured persons
- 1
- Post-event summary
According to source, a worker was only slightly injured by incandescent dust jets. The furnace was shut down for 25 hours and the dust collector for 15 days, during which 87 t of dust (lime) was released into the environment.
Residents were inconvenienced and traffic on the nearby highway disrupted.- Emergency action
The disaster was controlled in 15 minutes thanks to the intervention of a dozen internal
firefighters.
Lesson Learnt
- Lesson Learnt
The source does not report improvement requirements. Nevertheless, the inadequate manual de-clogging intervention shows that better procedure and better safety training are needed.
In-depth data
- Release type
- gas mixture
- Involved substances (% vol)
- powder and CO+H2 mixture
- Release temperature [°C]
- 25
- Probable IGNITION SOURCE
- Explosion type
- Detonation
References
- Sources categories
- ARIA
- Reference & weblink
Event description in the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/9944/
(accessed September 2020)