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Clean Hydrogen Partnership

Release of hydrocarbons and hydrogen in a refinery

Event

Event ID
901
Quality
Description

The accident occurred on one of the heat exchangers of the hydrodesulphurisation unit.
The role of the exchanger , located between the charge pumps and the furnace, was to heat the charge using the hot products from the reactor. Before the exchanger, pressurised hydrogen is injected into the charge. The exchanger was equipped with interchangeable bundles mounted with deflector plates.

During a shutdown, some beams were mistakenly reassembled upside down. When the installation restarted and the compressor of the hydrogen circuit arrived at 75% of its capacity, one of the deflectors was blown off and obstructed the inlet of the exchanger. Consequently, the safety device of the compressor triggered the compressor stop and the pressure release valves released part of the contents.

Event Initiating system
Classification of the physical effects
Unignited Hydrogen Release
Nature of the consequences
leak no ignition
Macro-region
Europe
Country
France
Date
Component involved
heat exchanger (pipe)
Failure mode
rupture, no ignition
Initiating cause
wrong installation
Root CAUSE analysis

The reason for the over-pressurisation of the compressor and the pressure relief activation was the block of part of the gas flow into the heat exchanger tubes bundle.

A ROOT CAUSE component was a human error occurred when re-installing the exchanger's components inverted. However, an additional factor was the failure of the supervision and final inspection procedure to detect the mistake.

Root causes
Date entry in HIAD
01/01/2018

Facility

Application
Petrochemical industry
Sub-application
Hydrodesulphurisation process
Hydrogen supply chain stage
All components affected

heat exchanger

Process temperature range [C]
High temperature (100°C to 500°C)
Process pressure range [MPa]
medium to high pressure (10 to 50 MPa)
Location type
Open
Location
industrial area
Operational condition
Pre-event occurrences

The desulphurisation unit was restarted after a shutdown during which component of the heat exchanger unit were (wrongly) reinstalled

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

Part of the hydrocarbon load, including hydrogen, was released to the environment.

In-depth data

Release type
gas mixture
Involved substances (% vol)
H2,
hydrocarbons
Probable IGNITION SOURCE

References

Sources categories
ARIA
Reference & weblink

Original description of the event in database ARIA