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Clean Hydrogen Partnership

Explosion in a facility for boilers maintenance

Event

Event ID
838
Quality
Description

The explosion occurred during repair work on a boiler. A technician had previously descaled the device using hydrochloric acid (HCl), after which he performed the neutralisation step with soda and drained the passivated acid.
The significant scaling on the boiler required a second acid injection, followed by welding work, but this time the rest of the acid had not been drained from the boiler.
Hydrogen emitted by a metal + acid reaction was the cause of this accident. An employee wound up in hospital in a coma.
Labour inspection authorities noted that operating conditions were not respecting environmental protection requirements, i.e. failure to control discharge pH.
They also noted the absence of written procedures.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
France
Date
Component involved
heat exchanger (generic)
Failure mode
rupture & ignition
Initiating cause
accidental hydrogen formation
Root CAUSE analysis

INITIATING cause was failure to perform an operative step
This caused the formation of hydrogen from the reaction of hydrochloric acid with metals, in presence of a hot source (welding).
The absence of any written procedure hits at a poor management of the operation.

Root causes
Date entry in HIAD
01/01/2020

Facility

Application
Other
Sub-application
Boilers industry
Hydrogen supply chain stage
All components affected

Workshop for maintenance of boilers, hydochloric acid

Process temperature range [C]
ambient temperature (-50°C to +50°C)
Location type
Confined
Location
unknown
Operational condition
Pre-event occurrences

The explosion occurred during repair work on a boiler.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
1
Post-event summary

An employee wound, in hospital in a coma.

Official legal action

Labour inspection authorities noted that operating conditions were not favourable towards environmental protection, i.e. failure to control discharge pH, absence of written procedures.

In-depth data

Release type
Gas-liquid-solid mixture
Involved substances (% vol)
NaHO,
metals,
H2
Release temperature [°C]
25
Probable IGNITION SOURCE
Explosion type

References

Sources categories
ARIA
Reference & weblink

ARIA data base
event no. 28569