Event
- Event ID
- 838
- Quality
- Description
The explosion occurred during repair work on a boiler. A technician had previously descaled the device using hydrochloric acid (HCl), after which he performed the neutralisation step with soda and drained the passivated acid.
The significant scaling on the boiler required a second acid injection, followed by welding work, but this time the rest of the acid had not been drained from the boiler.
Hydrogen emitted by a metal + acid reaction was the cause of this accident. An employee wound up in hospital in a coma.
Labour inspection authorities noted that operating conditions were not respecting environmental protection requirements, i.e. failure to control discharge pH.
They also noted the absence of written procedures.- Event Initiating system
- Classification of the physical effects
- Hydrogen Release and Ignition
- Nature of the consequences
- Macro-region
- Europe
- Country
- France
- Date
- Component involved
- heat exchanger (generic)
- Failure mode
- rupture & ignition
- Initiating cause
- accidental hydrogen formation
- Root CAUSE analysis
INITIATING cause was failure to perform an operative step
This caused the formation of hydrogen from the reaction of hydrochloric acid with metals, in presence of a hot source (welding).
The absence of any written procedure hits at a poor management of the operation.- Root causes
- Date entry in HIAD
- 01/01/2020
Facility
- Application
- Other
- Sub-application
- Boilers industry
- Hydrogen supply chain stage
- All components affected
Workshop for maintenance of boilers, hydochloric acid
- Process temperature range [C]
- ambient temperature (-50°C to +50°C)
- Location type
- Confined
- Location
- unknown
- Operational condition
- Pre-event occurrences
The explosion occurred during repair work on a boiler.
Emergency & Consequences
- Number of fatalities
- 0
- Number of injured persons
- 1
- Post-event summary
An employee wound, in hospital in a coma.
- Official legal action
Labour inspection authorities noted that operating conditions were not favourable towards environmental protection, i.e. failure to control discharge pH, absence of written procedures.
In-depth data
- Release type
- Gas-liquid-solid mixture
- Involved substances (% vol)
- NaHO,
metals,
H2 - Release temperature [°C]
- 25
- Probable IGNITION SOURCE
- Explosion type
References
- Sources categories
- ARIA
- Reference & weblink
ARIA data base
event no. 28569