Event
- Event ID
- 663
- Quality
- Description
An explosion occurred in a nitrogen wash cold box (outside the equipment) after a several day cold shutdown followed by a derime with nitrogen. It is assumed that ice may have split tubes permitting carbon monoxide and hydrogen to leak into the perlite installation. It is likewise assumed that the insulation had channelled and had many voids.
However, the insulation was continuously purged with nitrogen and the mechanism of the explosion is still unknown.- Event Initiating system
- Classification of the physical effects
- Hydrogen Release and Ignition
- Nature of the consequences
- Macro-region
- North America
- Country
- United States
- Date
- Component involved
- pipe (weld)
- Failure mode
- rupture & ignition
- Initiating cause
- material degradation (generic)
- Root CAUSE analysis
The INITIATING CAUSE were cracks in aluminium welds which leaked hydrogen cumulating in the cold box.
A CONTRIBUTING FACTOR was the cold weather which could have caused the formation of ice. Since the cold box thermal insulation, consisting of perlite, was purged with nitrogen, it is unclear why hydrogen and CO could form an explosive atmosphere.
The ROOT CAUSE is not provided. It could nevertheless plausibly attributed to design and/or manufacturing (welding) error.
- Root causes
- Date entry in HIAD
- 01/01/2020
Facility
- Application
- Chemical industry
- Sub-application
- cryogenic separation of H2 feed gas
- Hydrogen supply chain stage
- All components affected
cold box
- Process temperature range [C]
- cryogenic temperature (below -50°C)
- Location type
- Unknown
- Location
- unknown
- Operational condition
- Description of the facility/unit/process/substances
DECRITION OF THE PROCESS
A "derime" is a maintenance procedure used to remove frozen impurities from a cryogenic system, such as a nitrogen or air separation unit. This is done by warming up the equipment and flowing a warm, dry gas through it to melt and purge any accumulated moisture, carbon dioxide, or other contaminants that would otherwise freeze and block the system. The terms "derime," "defrost," "de-ice," and "thaw" are often used interchangeably for this process.
Emergency & Consequences
- Number of fatalities
- 0
- Number of injured persons
- 0
- Currency
- US$
- Property loss (onsite)
- 1.900.000
In-depth data
- Release type
- gas mixture
- Involved substances (% vol)
- H2
CO - Probable IGNITION SOURCE
- Explosion type
References
- Sources categories
- ICHEME
- Reference & weblink
Event description extracted from the UK database ICHEME in PDF.
The
https://www.icheme.org/knowledge/safety-centre/resources/accident-data/
(accessed October 2020)Table III of Appendix A of Zalosh and Short
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978
https://www.osti.gov/biblio/6566131
(accessed September 2020)LOSS PREVENTION, VOL. 3.