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Clean Hydrogen Partnership

Leak Fir from the a hydrogen flange in a synthetic adhesives production plant

Event

Event ID
633
Quality
Description

This accident occurred at the unit producing synthetic adhesives by adding hydrogen to petroleum resin under high temperature and pressure. Hydrogen was added to the reaction via a supply pipe at the bottom of the reactor.
Hydrogen leaked from a flange of the check valve attached to the hydrogen supply pipe and ignited due to static electricity. The leak was due to the deformation of the flange gasket, made of aluminium. The aluminium had deformed due to the high temperature, reducing the tightness of the flange.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
Asia
Country
Japan
Date
Component involved
flange (bolts)
Failure mode
leak & ignition
Initiating cause
loss of tightness (thermal stress/cycling)
Root CAUSE analysis

The INITIATING CAUSE was the deformation of the gasket of a flange on the hydrogen supply pipe.
The KHK report attributes the ROOT CAUSE to the wrong choice of the gasket material. The report does not specify if this was due to a wrong installation (human error) or a lack of clarity of procedures.

Root causes
Date entry in HIAD
01/01/2020

Facility

Application
Chemical industry
Sub-application
resins production
Hydrogen supply chain stage
All components affected

gasket, flange, check valve,

Location type
Unknown
Location
industrial area
Operational condition

Emergency & Consequences

Number of fatalities
0
Number of injured persons
1
Post-event summary

minor injury

In-depth data

Release type
gas
Involved substances (% vol)
H2 100%
Probable IGNITION SOURCE

References

Sources categories
KHK
Reference & weblink

High Pressure Gas Accident Cases Database of the KHK (High Pressure Gas Safety Association):
https://www.khk.or.jp/public_information/incident_investigation/hpg_inc…
(accessed May 2025)