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Clean Hydrogen Partnership

Explosion at a sodium chlorate production unit

Event

Event ID
585
Quality
Description

A lack of nitrogen purge in empty electrolytic chlorate cells allowed hydrogen to accumulate and to form a hydrogen-chlorine explosive mixture.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Component involved
electrolytic cell
Failure mode
internal explosion
Initiating cause
inadequate or no purge
Root causes
Unknown
Date entry in HIAD
28/01/2026

Facility

Application
Chemical industry
Sub-application
sodium chlorite production
Hydrogen supply chain stage
Location type
Confined
Location
unknown
Operational condition
UNKNOWN
Description of the facility/unit/process/substances

DESCRIPTION OF THE PROCESS
“Sodium chlorate is an inorganic compound produced by the electrolysis of concentrated sodium chloride solutions (NaCl).
The overall reaction can be simplified to the equation:
NaCl + 3 H2O → NaClO3 + 3 H2

[https://en.wikipedia.org/wiki/Sodium_chlorate]

Emergency & Consequences

Number of fatalities
0
Number of injured persons
1
Currency
US$
Property loss (onsite)
7.000

In-depth data

Probable IGNITION SOURCE
Explosion type

References

Sources categories
Zalosh
Reference & weblink

Table II - Industrial Incidetns of Appendix A of Zalosh and Short
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978
https://www.osti.gov/biblio/6566131
(accessed September 2020)