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Clean Hydrogen Partnership

Explosion in a chlorine production plan.

Event

Event ID
488
Quality
Description

The vent occurred a chlorine electrolyser using mercury amalgam. Hydrogen entered the chlorine header and igniting spontaneously causing explosion. It did not vent properly, and the hydrogen analyzer was provided but not used.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Component involved
electrolytic cell
Failure mode
internal explosion
Initiating cause
malfunctioning (electrolyser, cross-over)
Root CAUSE analysis

The fact that a hydrogen analyser was available but not used suggests an inadequate control of the process, which may have its root in a failure to follow procedures, and/or failure in management of hazards.

Root causes
Date entry in HIAD
28/01/2026

Facility

Application
Chemical industry
Sub-application
chlorine production
Hydrogen supply chain stage
Process temperature range [C]
Above ambient temperature (50°C to 100°C)
Location type
Confined
Location
unknown
Operational condition

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Currency
US$
Property loss (onsite)
2.500

In-depth data

Release type
gas mixture
Involved substances (% vol)
H2,
Cl2
Release temperature [°C]
25
Probable IGNITION SOURCE
Explosion type

References

Sources categories
Zalosh
Reference & weblink

Table II - Industrial Incidents of Appendix A of Zalosh and Short
COMPARATIVE ANALYSIS OF HYDROGEN FIRE AND EXPLOSION INCIDENTS
Quarterly Report No. 2 for Period December 1, 1977 - February 28, 1978
https://www.osti.gov/biblio/6566131
(accessed September 2020)