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Clean Hydrogen Partnership

Syngas fire at a shift catalyst reactor

Event

Event ID
319
Quality
Description

A small leak of syngas (a mixture mainly consisting of hydrogen and carbon monoxide) resulted in a localised fire. The location was a bolted flange on the outlet carbon steel pipework of the High Temperature Shift Catalyst Vessel.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
fire
Macro-region
Europe
Country
United Kingdom
Date
Component involved
flange (gasket)
Failure mode
leak & ignition
Initiating cause
unknown
Root causes
Unknown
Date entry in HIAD
28/02/2009

Facility

Application
Chemical industry
Sub-application
Ammonia production
Hydrogen supply chain stage
All components affected

flange,
High Temperature Shift Catalyst Vessel.

Process temperature range [C]
High temperature (100°C to 500°C)
Location type
Unknown
Location
industrial area
Operational condition

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Emergency action

The incident was identified and quickly brought under control by initiating a controlled shutdown of the plant where the flame size was reduced and ultimately extinguished.
It was not considered necessary to initiate the plant Emergency Shutdown procedure. The leak occurred at an elevated and un-occupied position on the vessel.

Since the leak occurred in the in the "hot front end" of the plant, a controlled the cool down was necessary, for 24 hours, after which the gasket could be replaced. The restart took around 36 to 48 hours.

In-depth data

Release type
gas mixture
Involved substances (% vol)
H2, CO
Probable IGNITION SOURCE

References

Sources categories
HSE
Reference & weblink

Event description provided by HSE, original source confidential