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Clean Hydrogen Partnership

Explosion when working on a hydrogen cylinder

Event

Event ID
299
Quality
Description

A process operator was working on a hydrogen tank in a mechanical workshop.
The goal of the onoging operation was the removal of the collar from a hydrogen cylinder. An electric crosscut saw was used to make two diagonal cuts in the collar of the cylinder before removal of the collar with a hammer and chisel.
An angle grinder was also occasionally used when a collar was proving difficult to remove.
The investigation found out that the purging of the cylinder had not been performed, or performed only partially, leaving high concentrations of hydrogen.
Sparks from the cutting process caused ignition of hydrogen present in container.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
Europe
Country
United Kingdom
Date
Component involved
CGH2 cylinder(s)
Failure mode
erroneous release & ignition
Initiating cause
inadequate or no purge
Root CAUSE analysis

INITIATING cause: Rest hydrogen in cylinder while starting mechanical work
ROOT CAUSE: no purging, thus failing to execute correctly procedures, or shortcoming in procedure, and lack of risk management throughout the process.

Root causes
Date entry in HIAD
28/02/2009

Facility

Application
Unknown
Sub-application
GH2 stationary storage
Hydrogen supply chain stage
All components affected

Hydrogen cylinder, mechanical workshop

Process temperature range [C]
ambient temperature (-50°C to +50°C)
Process pressure range [MPa]
ambient pressure (around 0.1 MPa)
Location type
Unknown
Location
unknown
Operational condition

Emergency & Consequences

Number of fatalities
0
Number of injured persons
1

Lesson Learnt

Lesson Learnt

This is a case of wrong or ineffective purging. Failure in performing a proper purging, able to eliminate any possibility of ignition, is a recurrent event in industrial environment dealing with flammable gases. In this specific case, purging was carried out in different locations of the company, what caused lack of proper information and increased the risk of confusion on the status of the cylinders. Moreover, little attention had been given to the risks to which the workers were exposed when working with hydrogen cylinders.

Corrective Measures

:
The following measures were taken since the accident:
(1) All cylinders to be purged at this location and undergo batch control of purging,
(2) A physical barrier erected to stop the operator standing in line with the cylinder outlet.

In-depth data

Release type
gas
Involved substances (% vol)
H2 100%
Release temperature [°C]
25
Probable IGNITION SOURCE
Explosion type

References

Sources categories
HSE
Reference & weblink

Event description provided by HSE, original source confidential