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Clean Hydrogen Partnership

Explosion and fire in a fertiliser plant

Event

Event ID
196
Quality
Description

The explosion occurred in the compressors unit of the plant. Witnesses reported a cloud of yellow smoke and a fire ball at its bottom.
This first event was followed by a fire fed by a hydrogen pipe (5.5 t of hydrogen was present in the system). The fire brigade confined it until its natural extinction.

A negligible amount of ammonia was probably released to the environment. No injured but a considerable materials damage: the plant remained closed for one week and specialised work had to be done for the removal of asbestos contained in a wall which was destroyed by the explosion.
It is suspected that the cause of the first incident was a weld on the hydrogen pipe which failed due to fatigue.

Event Initiating system
Classification of the physical effects
Hydrogen Release and Ignition
Nature of the consequences
Macro-region
North America
Country
United States
Date
Component involved
compressor / booster / pump
Failure mode
leak & ignition
Initiating cause
unknown
Root CAUSE analysis

The INITIATING (or the contributing) cause is suspected to be the failure of the welding of the hydrogen pipe.
Nothing is known on the root cause, but the organisation has continued the operation, while not able to identify the original of the incidents.

Root causes
Date entry in HIAD
01/01/2021

Facility

Application
Chemical industry
Sub-application
Fertilisers production
Hydrogen supply chain stage
All components affected

compressor, hydrogen pipe, ammonia reactor

Process temperature range [C]
Above ambient temperature (50°C to 100°C)
Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

other small incidents had occurred during the preceding 7 days : the plant was shut down one week before due to the malfunctioning of a compressor and a boiler. When restarting a small explosion had occurred. The plant was restarted 2 days later and stopped again the next day due to the malfunctioning of an other compressor. After one day of control, the plant is again restarted and the main explosion occurred.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
0
Post-event summary

Asbestos was released by the destruction of a wall. Analysis were made to determine if welded part were strained.

Emergency action

The fire brigade confined the fire until its natural extinction.

In-depth data

Release type
gas mixture
Involved substances (% vol)
H2
NH3
Release temperature [°C]
25
Probable IGNITION SOURCE
Explosion type

References

Sources categories
ARIA
Reference & weblink

Event 18302 o the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/18302_en/?lang=…
(accessed September 2020)