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Clean Hydrogen Partnership

Release at a cooling system of a polymerisation plant

Event

Event ID
81
Quality
Description

While de-plugging a cooling circuit, a blockage suddenly released, causing a heavy movement of a flexible hose connected to the system. The flexible hose hit several small pipes and one employee standing nearby. Due to the broken pipework there was a release of hydrogen and butane for about five minutes. Sprinkler systems were activated, no ignition occurred.

Event Initiating system
Classification of the physical effects
Unignited Hydrogen Release
Nature of the consequences
leak no ignition
Macro-region
Europe
Country
European Union
Date
Component involved
pipe (generic)
Failure mode
rupture, no ignition
Initiating cause
impact, rollover, crash
Root CAUSE analysis

The INITIATING cause was a mechanical failure, the root cause is not reported. However, an abnormal situation had occurred previously during the day, hinting probably at some human and/or organisation error.

Root causes
Date entry in HIAD
28/02/2009

Facility

Application
Chemical industry
Sub-application
Polymerisation plant
Hydrogen supply chain stage
All components affected

cooling circuit, hose, pipes, Plastics and rubber manufacture

Location type
Unknown
Location
industrial area
Operational condition
Pre-event occurrences

De-blocking of a cooler was done by using water at high pressure, but with great difficulties. During the day, a nitrogen feed had been temporarily opened out of fear for an explosive atmosphere in the receiving tank-truck. When the water pressure was put on the system again, a nitrogen plug was probably compressed. When the blockage released, the plug was ejected with great velocity, causing the connected flexible hose to move violently.

Emergency & Consequences

Number of fatalities
0
Number of injured persons
1
Post-event summary

One employee standing nearby was hit by the flexible hose. Loss of hydrogen and butene for several minutes. Limited loss of polyethylene powder and hexane. Estimated production loss: 7 days.

Emergency action

Sprinkler systems were activated to contain hydrocarbon cloud and to prevent ignition. Leaking pipes were blocked after five minutes. The injured employee was hospitalised.

Emergency evaluation

An explosion could have destroyed the entire polymerisation unit.

Lesson Learnt

Lesson Learnt

This is a classic case of injuries and damages caused by a whiplash of high-pressure hoses. Best practice and work procedures require the use of hose whip restraints (whip checks) to secure the hose and prevent it from whipping during a failure. It is recommended to regularly check if the hoses are securely anchored and to wear appropriate PPE. A lose, unrestrained hose shall never be operated.

In-depth data

Release type
gas mixture
Involved substances (% vol)
C4H8
H2
Probable IGNITION SOURCE

References

Sources categories
eMARS
Reference & weblink

Event description in the European database eMARS (accessed December 2020)